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Phloroglucinol, anhydrous_Molecular_structure_CAS_108-73-6)
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Phloroglucinol, anhydrous

Catalog No. B25502 Name Alfa Aesar
CAS Number 108-73-6 Website
M. F. C6H6O3 Telephone
M. W. 126.11004 Fax
Purity 98% Email
Storage Chembase ID: 89823

SYNONYMS

Title
无水间苯三酚
IUPAC name
benzene-1,3,5-triol
IUPAC Traditional name
phloroglucinol
Synonyms
1,3,5-Trihydroxybenzene
1,3,5-Benzenetriol, anhydrous

DATABASE IDS

EC Number 203-611-2
MDL Number MFCD00002286
Merck Index 147328
CAS Number 108-73-6
Beilstein Number 1341907

PROPERTIES

Purity 98%
Melting Point 215-220°C
GHS Pictograms GHS07
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
GHS Precautionary statements P261-P305+P351+P338-P302+P352-P321-P405-P501A
Risk Statements 36/37/38
RTECS SY1050000
Safety Statements 26-37
Storage Warning Light Sensitive & Hygroscopic
TSCA Listed

DETAILS

REFERENCES

  • Reacts with mono- or dimethylamine in DMF-water, with displacement of one of the OH groups, to give 5-aminoresorcinols: Helv. Chim. Acta, 56, 510 (1973).
  • The electron-rich nucleus undergoes acylation with nitriles under mild Lewis acid catalysis, to give ketones (Houben-Hoesch reaction).
  • Selective monobromination cannot be achieved conventionally. For bromination-debromination protocols for the preparation of the mono- and di-brominated derivatives, see: Can. J. Chem., 67, 335 (1989).