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2-Nitrobenzenesulfenyl chloride_Molecular_structure_CAS_7669-54-7)
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2-Nitrobenzenesulfenyl chloride

Catalog No. B23627 Name Alfa Aesar
CAS Number 7669-54-7 Website
M. F. C6H4ClNO2S Telephone
M. W. 189.61946 Fax
Purity 98% Email
Storage Chembase ID: 103428

SYNONYMS

Title
2-硝基苯亚磺酰氯
IUPAC name
1-(chlorosulfanyl)-2-nitrobenzene
IUPAC Traditional name
1-(chlorosulfanyl)-2-nitrobenzene
Synonyms
2-Nitrophenylsulfenyl chloride

DATABASE IDS

Beilstein Number 473741
CAS Number 7669-54-7
EC Number 231-644-2
MDL Number MFCD00007128

PROPERTIES

Purity 98%
Melting Point 72-75°C
GHS Pictograms GHS05
GHS Hazard statements H314-H318
European Hazard Symbols Corrosive Corrosive (C)
GHS Precautionary statements P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A
Risk Statements 34
Safety Statements 26-36/37/39-45
Storage Warning Moisture Sensitive
TSCA Listed
Hazard Class 8
UN Number UN3261
Packing Group II

DETAILS

REFERENCES

  • The chemistry of sulfenyl halides has been reviewed: Synthesis, 563, 617 (1971).
  • Reagent for N-protection as N-2-nitrophenylsulfenyl (Nps) derivatives, in amino acids and peptides: J. Am. Chem. Soc., 85, 3660 (1963); 87, 99 (1965); Biochemistry, 7, 971, 980 (1968); Synthesis, 512 (1985); Helv. Chim. Acta, 66, 602 (1983), and nucleosides: J. Org. Chem., 54, 2321 (1989). The Nps group is readily cleaved by dilute acid. For cleavage with thioacetamide, see: Helv. Chim. Acta, 49, 1330 (1966).