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3-Bromofuran

Catalog No. B23543 Name Alfa Aesar
CAS Number 22037-28-1 Website
M. F. C4H3BrO Telephone
M. W. 146.97002 Fax
Purity 97%, stab. with 0.5% calcium carbonate Email
Storage Chembase ID: 80499

SYNONYMS

Title
3-溴呋喃
IUPAC name
3-bromofuran
IUPAC Traditional name
3-bromofuran

DATABASE IDS

Beilstein Number 105337
EC Number 244-744-6
CAS Number 22037-28-1
MDL Number MFCD00005347

PROPERTIES

Purity 97%, stab. with 0.5% calcium carbonate
Boiling Point 102-104°C
Density 1.635
Flash Point 3°C(37°F)
Refractive Index 1.4960
GHS Pictograms GHS02
GHS Pictograms GHS07
GHS Hazard statements H225-H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
European Hazard Symbols Flammable Flammable (F)
GHS Precautionary statements P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
Risk Statements 11-36/37/38
Safety Statements 9-16-26-37-60
TSCA Listed
Hazard Class 3
UN Number UN1993
Packing Group II

DETAILS

REFERENCES

  • Precursor of 3-lithiofuran by treatment with n-BuLi at low temperatures. Isomerization to 2-lithiofuran tends to occur above -40o: Tetrahedron, 46, 1199 (1990). With LDA at -78o, selective 2-lithiation can be achieved to give 3-bromo-2-lithiofuran, which has been used in synthesis of phenethylthiazolylthiourea (PETT) analogues as potential HIV-1 reverse transcriptase inhibitors: J. Med. Chem., 39, 4261 (1996).