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Triethyl 2-phosphonopropionate

Catalog No. B23261 Name Alfa Aesar
CAS Number 3699-66-9 Website
M. F. C9H19O5P Telephone
M. W. 238.217921 Fax
Purity 98% Email
Storage Chembase ID: 91243

SYNONYMS

Title
2-膦酰丙酸三乙脂
IUPAC name
ethyl 2-(diethoxyphosphoryl)propanoate
IUPAC Traditional name
ethyl 2-(diethoxyphosphoryl)propanoate
Synonyms
Diethyl 1-(ethoxycarbonyl)ethanephosphonate
2-Phosphonopropionic acid triethyl ester

DATABASE IDS

Beilstein Number 1786994
MDL Number MFCD00009159
EC Number 223-033-4
CAS Number 3699-66-9

PROPERTIES

Purity 98%
Boiling Point 143-144°C/12mm
Density 1.111
Flash Point 88°C(190°F)
Refractive Index 1.4320
GHS Hazard statements H227
GHS Precautionary statements P210-P280-P370+P378A-P403+P235-P501A
TSCA Listed

DETAILS

REFERENCES

  • Wadsworth-Emmons precursor of methacrylic esters (see Triethyl phosphonoacetate, A14120 and Appendix 1). Lithiation followed by acylation with perfluoroalkanoic anhydrides gives a perfluoroacyl intermediate which, with an organolithium reagent, leads stereoselectively to a trifluoroalkylated ɑ?-unsaturated ester: J. Fluorine Chem., 89, 141 (1998):