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2-Hexyne

Catalog No. B22405 Name Alfa Aesar
CAS Number 764-35-2 Website
M. F. C6H10 Telephone
M. W. 82.1436 Fax
Purity 98+% Email
Storage Chembase ID: 89892

SYNONYMS

Title
2-已炔
IUPAC name
hex-2-yne
IUPAC Traditional name
2-hexyne

DATABASE IDS

EC Number 212-117-6
MDL Number MFCD00009470
CAS Number 764-35-2
Beilstein Number 1731542

PROPERTIES

Purity 98+%
Boiling Point 84-86°C
Density 0.736
Flash Point -10°C(14°F)
Melting Point -90°C
Refractive Index 1.4140
GHS Pictograms GHS02
GHS Pictograms GHS07
GHS Pictograms GHS08
GHS Hazard statements H225-H304-H315-H319-H335
European Hazard Symbols X
European Hazard Symbols Flammable Flammable (F)
GHS Precautionary statements P210-P301+P310-P303+P361+P353-P305+P351+P338-P405-P501A
Risk Statements 11-36/37/38-65
Safety Statements 9-16-26-29-33-37-62
TSCA Listed
Hazard Class 3
UN Number UN3295
Packing Group II

DETAILS

REFERENCES

  • 2-Alkynes are metallated almost exclusively at the terminal position by t-BuLi + TMEDA in ether. Subsequent reaction with, e.g. TMS chloride gives propargylic silanes: Synthesis, 111 (1984).
  • On heating under pressure with norbornene and CO in the presence of Dodecacarbonyltriruthenium, 10507, alkynes undergo aromatization to give condensed hydroquinones: Organometallics, 17, 766 (1998):