Chlorotitanium triisopropoxide

• Catalog No.: B21914
• CAS Number: 20717-86-6
• M. F.: C9H21ClO3Ti
• M. W.: 260.58124
• Purity: 95%

SYNONYMS

• Title: 三异丙氧化氯钛
• IUPAC name: titanium(4+) ion tris(propan-2-olate) chloride
• IUPAC Traditional name: titanium(4+) ion tris(propan-2-olate) chloride
• Synonyms: Titanium chloride triisopropoxide; Chlorotriisopropoxytitanium

DATABASE IDS

• MDL Number: MFCD00009861
• CAS Number: 20717-86-6

PROPERTIES

• Purity: 95%
• Boiling Point: 63-66°C/0.1mm
• Density: 1.091
• Flash Point: 31°C(87°F)
• Melting Point: 37-44°C
• GHS Hazard statements: H314-H318-H228
• European Hazard Symbols: Corrosive (C)
• European Hazard Symbols: Flammable (F)
• GHS Precautionary statements: P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
• Risk Statements: 11-34
• Safety Statements: 26-36/37/39-45
• Storage Warning: Moisture Sensitive
• TSCA Listed: 是
• Hazard Class: 8
• UN Number: UN2921
• Packing Group: II

REFERENCES

• Reacts with the Li enolates of ketones to give Ti(IV) enolates which undergo the aldol condensation with pronounced erythro-selectivity: Tetrahedron Lett., 22, 4691 (1981). This selectivity can be extended to aldehydes by using the Li derivatives of their N,N-dimethylhydrazones: Angew. Chem. Int. Ed., 21, 864 (1982).
• In combination with cyclopentylmagnesium bromide, forms a Ti(II) species which mediates the reaction of vinyltributyltin with esters or amides to give trisubstituted cyclopropylstannanes with high diastereoselectivity: J. Org. Chem., 63, 9135 (1998).