Tris(2-aminoethyl)amine

• Catalog No.: B21789
• CAS Number: 4097-89-6
• M. F.: C6H18N4
• M. W.: 146.23392
• Purity: 97%

SYNONYMS

• Title: 三(2-氨乙基)胺
• IUPAC name: tris(2-aminoethyl)amine
• IUPAC Traditional name: tren
• Synonyms: 2,2',2''-Triaminotriethylamine

DATABASE IDS

• Beilstein Number: 1739626
• CAS Number: 4097-89-6
• EC Number: 223-857-4
• MDL Number: MFCD00008177

PROPERTIES

• Purity: 97%
• Boiling Point: 102°C/0.05mm
• Density: 0.978
• Flash Point: >110°C(230°F)
• Refractive Index: 1.4969
• GHS Hazard statements: H301-H310-H314-H318
• European Hazard Symbols: Toxic (T)
• GHS Precautionary statements: P280-P305+P351+P338-P309-P310
• Risk Statements: 22-24-34
• RTECS: KH8587082
• Safety Statements: 26-36/37/39-45
• Storage Warning: Air Sensitive & Hygroscopic
• TSCA Listed: 是
• Hazard Class: 8
• UN Number: UN2922
• Packing Group: II

REFERENCES

• Reagent for rapid cleavage of the Fmoc group in peptide synthesis, particularly recommended in conjunction with Fmoc-protected acid chlorides as the active species: J. Org. Chem., 55, 1673 (1990). For a review of peptide synthesis via amino acid halides, see: Acc. Chem. Res., 29, 268 (1996). For peptide reagents, see Appendix 6.
• Reaction with aryl isocyanates and isothiocyanates gives tris-urea and -thiourea derivatives which have been evaluated as phosphate and sulfate receptors: Chem. Lett., 759 (1995).