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1,1'-Bis(diphenylphosphino)ferrocene_Molecular_structure_CAS_12150-46-8)
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1,1'-Bis(diphenylphosphino)ferrocene

Catalog No. B21166 Name Alfa Aesar
CAS Number 12150-46-8 Website
M. F. C34H28FeP2 Telephone
M. W. 554.378642 Fax
Purity 97% Email
Storage Chembase ID: 125081

SYNONYMS

Title
1,1'-双(二-苯基膦基)二茂铁
IUPAC name
λ2-iron(2+) ion bis(3-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide)
IUPAC Traditional name
λ2-iron(2+) ion bis(3-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide)
Synonyms
1,1'-Ferrocenebis(diphenylphosphine)
dppf

DATABASE IDS

EC Number 430-420-3
CAS Number 12150-46-8
MDL Number MFCD00001422

PROPERTIES

Purity 97%
Melting Point ca 182°C dec.
GHS Pictograms GHS07
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
GHS Precautionary statements P261-P305+P351+P338-P302+P352-P321-P405-P501A
Risk Statements 36/37/38
Safety Statements 26-37
Storage Warning Air Sensitive
TSCA Listed

DETAILS

REFERENCES

  • Hindered bidentate ligand used in, for example, the Ni-catalyzed Suzuki-type crossed coupling of arylboronic acids with aryl mesylates to give biaryls: J. Org. Chem., 60, 1060, 1066 (1995), and of thiophenolates with aryl mesylates to give unsymmetrical diaryl sulfides: J. Org. Chem., 60, 6895 (1995).