Perfluoro(decahydronaphthalene), cis + trans

• Catalog No.: A18288
• CAS Number: 306-94-5
• M. F.: C10F18
• M. W.: 462.0782576
• Purity: 95%

SYNONYMS

• Title: 全氟(十氢化萘),顺式+反式
• IUPAC name: octadecafluoro-decahydronaphthalene
• IUPAC Traditional name: perfluorodecalin
• Synonyms: Octadecafluorodecalin; Octadecafluoro(decahydronaphthalene)

DATABASE IDS

• EC Number: 206-192-4
• MDL Number: MFCD00010626
• Beilstein Number: 2067113
• CAS Number: 306-94-5
• Merck Index: 144183

PROPERTIES

• Purity: 95%
• Boiling Point: 141-142°C
• Density: 1.940
• Melting Point: -10 to -7°C
• Refractive Index: 1.3145
• RTECS: QJ3175000
• TSCA Listed: 是

REFERENCES

• The ability of perfluorinated solvents to solubilize gases, together with their unique phase properties, have been exploited in a system for oxidation of aldehydes to acids, sulfides to sulfoxides and sulfones, and alkenes to epoxides. The reactions are carried out in the presence of dissolved O₂, using a transition metal (Ru, Ni) catalyst with perfluorinated ligands, in a perfluoro(decahydronaphthalene)/toluene solvent mixture under monophasic conditions at 64^oC. On cooling, phase separation takes place, enabling the product to be isolated from the toluene phase, and the catalyst system to be recycled in the fluorous phase: Angew. Chem. Int. Ed., 36, 1454 (1997).