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2,6-Difluorobenzyl bromide_Molecular_structure_CAS_85118-00-9)
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2,6-Difluorobenzyl bromide

Catalog No. A17434 Name Alfa Aesar
CAS Number 85118-00-9 Website
M. F. C7H5BrF2 Telephone
M. W. 207.0154064 Fax
Purity 97+% Email
Storage Chembase ID: 9102

SYNONYMS

Title
2,6-二氟苄基溴
IUPAC name
2-(bromomethyl)-1,3-difluorobenzene
IUPAC Traditional name
2-(bromomethyl)-1,3-difluorobenzene
Synonyms
alpha-Bromo-2,6-difluorotoluene

DATABASE IDS

CAS Number 85118-00-9
EC Number 285-652-6
Beilstein Number 2083943
MDL Number MFCD00000329

PROPERTIES

Purity 97+%
Density 1.600
Flash Point >110°C(230°F)
Melting Point 49-53°C
GHS Pictograms GHS05
GHS Hazard statements H314-H318
European Hazard Symbols Corrosive Corrosive (C)
GHS Precautionary statements P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A
Risk Statements 34
Safety Statements 20-26-36/37/39-45-60
TSCA Listed
Hazard Class 8
UN Number UN1759
Packing Group III

DETAILS

REFERENCES

  • Reagent for protection of alcohols as 2,6-difluorobenzyl ethers which can be formed in the presence of Ba(OH)2 in DMF: Helv. Chim. Acta, 79, 1159 (1996). Unlike benzyl ethers, these are stable during cationic reactions. They can be cleaved by dissolving metal reduction (Ca/NH3): Chimia, 329 (1991).