Aliquat® 336

• Catalog No.: A17247
• CAS Number: 63393-96-4
• M. F.: C25H54ClN
• M. W.: 404.15596

SYNONYMS

• Title: Aliquat® 336
• IUPAC name: methyltrioctylazanium chloride
• IUPAC Traditional name: trioctylmethylammonium chloride
• Synonyms: Tricaprylylmethylammonium chloride; Methyltri-n-octylammonium chloride

DATABASE IDS

• CAS Number: 63393-96-4
• EC Number: 264-120-7
• MDL Number: MFCD00011862

PROPERTIES

• Boiling Point: >240°C
• Density: 0.880
• Flash Point: 132°C(269°F)
• Refractive Index: 1.4465
• GHS Hazard statements: H301-H315-H318-H400-H410
• European Hazard Symbols: X
• European Hazard Symbols: Nature polluting (N)
• GHS Precautionary statements: P280-P301+P310-P305+P351+P338-P302+P352-P405-P501A
• Risk Statements: 22-38-41-50/53
• RTECS: BR8575000
• Safety Statements: 23-26-36/37/39-57-60
• Storage Warning: Hygroscopic
• TSCA Listed: 是
• Hazard Class: 6.1
• UN Number: UN2810
• Packing Group: III

REFERENCES

• Mixture of C₈-C₁₀; predominantly C₈.
• Aliquat is a registered trademark of Cognis Corporation.
• Widely used lipophilic phase-transfer catalyst. Catalyzes the synthesis of long-chain alkyl azides from the bromides in water or formamide: Tetrahedron Lett., 30, 1245 (1989), the formation and saponification of hindered esters with KOH in the absence of solvent: J. Org. Chem., 51, 740 (1986), the solvent-free S_NAr reactions of halopyridines: Heterocycles, 32, 1947 (1991), and dehydrohalogenation of vic-dibromides to alkynes: Org. Prep. Proced. Int., 21, 232 (1989). Catalyzes the solvent-free liquid-liquid phase-transfer hydroboration of olefins, using aqueous NaBH₄: Synlett, 997 (2000). See Appendix 2.