N-(Trimethylsilyl)dimethylamine

• Catalog No.: A16550
• CAS Number: 2083-91-2
• M. F.: C5H15NSi
• M. W.: 117.2648
• Purity: 96%

SYNONYMS

• Title: N-(三甲基硅基)二甲胺
• IUPAC name: dimethyl(trimethylsilyl)amine
• IUPAC Traditional name: dimethylamino-trimethyl silane
• Synonyms: N,N-Dimethyltrimethylsilylamine; Dimethylaminotrimethylsilane

DATABASE IDS

• MDL Number: MFCD00008297
• Beilstein Number: 1731861
• CAS Number: 2083-91-2
• EC Number: 218-222-3

PROPERTIES

• Purity: 96%
• Boiling Point: 86-87°C
• Density: 0.732
• Flash Point: -19°C(-3°F)
• Refractive Index: 1.3970
• GHS Hazard statements: H225-H314-H318
• European Hazard Symbols: Corrosive (C)
• European Hazard Symbols: Flammable (F)
• GHS Precautionary statements: P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
• Risk Statements: 11-34
• Safety Statements: 16-26-36/37/39-45
• Storage Warning: Moisture Sensitive
• TSCA Listed: 是
• Hazard Class: 3
• UN Number: UN2733
• Packing Group: II

REFERENCES

• Reagent for siliylation of a wide range of functional groups, without the need for added base, useful for amino acids: J. Chromat. Sci., 7, 704 (1969). In the presence of the hindered ligand 2-(Di-tert-butylphosphino)biphenyl, L19758, Pd-catalyzed cross-coupling reactions with aryl halides to give substituted N,N-dimethylanilines have been effected: Chem. Commun., 1976 (2004).