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Benzyl phenyl sulfide

Catalog No. A16171 Name Alfa Aesar
CAS Number 831-91-4 Website
M. F. C13H12S Telephone
M. W. 200.29938 Fax
Purity 98% Email
Storage Chembase ID: 109245

SYNONYMS

Title
苄基苯基硫醚
IUPAC name
[(phenylsulfanyl)methyl]benzene
IUPAC Traditional name
[(phenylsulfanyl)methyl]benzene

DATABASE IDS

CAS Number 831-91-4
MDL Number MFCD00003066
EC Number 212-612-7
Beilstein Number 1909409

PROPERTIES

Purity 98%
Boiling Point 167-168°C/10mm
Flash Point >110°C(230°F)
Melting Point 39-42°C
TSCA Listed

DETAILS

REFERENCES

  • Has been used in a sequence for the introduction of an ortho-substituent into aromatic amines by base-induced rearrangement of an amino sulfonium salt: J. Am. Chem. Soc., 100, 7600 (1978):
  • Lithiation of phenylthioethers, (t-BuLi/HMPA) leads exclusively to the ɑ-lithio derivatives, which react with electrophiles such as alkyl halides and carbonyl compounds: Tetrahedron Lett., 1961 (1977).