Ethyl malonyl chloride

• Catalog No.: A15616
• CAS Number: 36239-09-5
• M. F.: C5H7ClO3
• M. W.: 150.56028
• Purity: 95%

SYNONYMS

• Title: 氯甲酰乙酸乙酯
• IUPAC name: ethyl 3-chloro-3-oxopropanoate
• IUPAC Traditional name: ethyl 3-chloro-3-oxopropanoate
• Synonyms: Ethyl (chloroformyl)acetate; Malonic acid monoethyl ester chloride

DATABASE IDS

• CAS Number: 36239-09-5
• EC Number: 252-934-5
• MDL Number: MFCD00000736
• Beilstein Number: 636215

PROPERTIES

• Purity: 95%
• Boiling Point: 83°C/22mm
• Density: 1.189
• Flash Point: 67°C(152°F)
• Refractive Index: 1.4290
• GHS Hazard statements: H314-H318-H227
• European Hazard Symbols: Corrosive (C)
• GHS Precautionary statements: P210-P260-P303+P361+P353-P305+P351+P338-P405-P501A
• Risk Statements: 14-34
• Safety Statements: 26-36/37/39-45
• Storage Warning: Moisture Sensitive
• TSCA Listed: 否
• Hazard Class: 8
• UN Number: UN3265
• Packing Group: II

REFERENCES

• Useful synthetic building block, e.g. in an oxazole synthesis: J. Med. Chem., 36, 3871 (1993):
  
• Formation of amides has been used in the syntheses of 1,2,4-triazine-3,6-diones, and of a vicinal tricarbonyl amide derivative of L-phenylalanine: J. Org. Chem., 60, 5992 (1995); 61, 1872 (1996).