9-Fluorenylmethanol

• Catalog No.: A15212
• CAS Number: 24324-17-2
• M. F.: C14H12O
• M. W.: 196.24448
• Purity: 99%

SYNONYMS

• Title: 9-芴甲醇
• IUPAC name: 9H-fluoren-9-ylmethanol
• IUPAC Traditional name: 9H-fluorene-9-methanol
• Synonyms: 9-Fluorenemethanol; 9-(Hydroxymethyl)fluorene

DATABASE IDS

• MDL Number: MFCD00001139
• CAS Number: 24324-17-2
• Beilstein Number: 2330017
• EC Number: 246-167-5

PROPERTIES

• Purity: 99%
• Melting Point: 102-106°C
• TSCA Listed: 是

REFERENCES

• Reagent for protection of carboxyl groups as their 9-fluorenylmethyl (Fm) esters, which improve solubility of the molecule in organic solvents. Fm esters can be formed, e.g. by the DCC-DMAP method: Tetrahedron Lett., 24, 281 (1983), or by imidazole-catalyzed transesterification of active esters of N-protected amino acids: Int. J. Pept. Prot. Res., 21, 196 (1983). Cleavage is by hydrogenolysis. See Appendix 6.
• Can also be used to protect phosphate groups in oligonucleotide synthesis: J. Chem. Soc., Chem. Commun., 803 (1973).