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Methyl phenyl sulfoxide

Catalog No. A15009 Name Alfa Aesar
CAS Number 1193-82-4 Website
M. F. C7H8OS Telephone
M. W. 140.20282 Fax
Purity 98+% Email
Storage Chembase ID: 87284

SYNONYMS

Title
甲基苯基亚砜
IUPAC name
methanesulfinylbenzene
IUPAC Traditional name
methyl phenyl sulfoxide

DATABASE IDS

EC Number 214-781-2
Beilstein Number 1904976
CAS Number 1193-82-4
MDL Number MFCD00002088

PROPERTIES

Purity 98+%
Boiling Point 93-94°C/0.3mm
Flash Point 86°C(186°F)
Melting Point 26-32°C
Refractive Index 1.5775
Storage Warning Hygroscopic
TSCA Listed

DETAILS

REFERENCES

  • Addition of the lithio-derivative to ketones followed by treatment with KO-t-Bu leads to allylic alcohols by sigmatropic rearrangement of the intermediate allyl sulfoxide: Synthesis, 640 (1980):
  • For the fluoro-Pummerer rearrangement to fluoromethyl phenyl sulfide, see: Diethylaminosulfur trifluoride, A11992.