Bromocyclopropane

• Catalog No.: A14996
• CAS Number: 4333-56-6
• M. F.: C3H5Br
• M. W.: 120.9758
• Purity: 99%

SYNONYMS

• Title: 溴代环丙烷
• IUPAC name: bromocyclopropane
• IUPAC Traditional name: bromocyclopropane
• Synonyms: Cyclopropyl bromide

DATABASE IDS

• Beilstein Number: 1900287
• CAS Number: 4333-56-6
• MDL Number: MFCD00001271
• EC Number: 224-375-7

PROPERTIES

• Purity: 99%
• Boiling Point: 68-70°C
• Density: 1.515
• Flash Point: -6°C(21°F)
• Refractive Index: 1.4600
• GHS Hazard statements: H225-H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• European Hazard Symbols: Flammable (F)
• GHS Precautionary statements: P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
• Risk Statements: 11-36/37/38
• Safety Statements: 16-26-29-33-37
• TSCA Listed: 是
• Hazard Class: 3
• UN Number: UN1993
• Packing Group: II

REFERENCES

• The Grignard reagent functions as an allyl anion equivalent in the reaction with thioacetals catalyzed by Dichlorobis(triphenylphosphine)nickel(II), 13930: J. Am. Chem. Soc., 111, 9119 (1989):
  
• The lithio-derivative reacts with Bis(cyclopentadienyl)titanium dichloride, A11456, to give bis(cyclopropyl)titanocene, which reacts with carbonyl compounds to give alkylidenecyclopropane derivatives: Tetrahedron Lett., 34, 943 (1993). Similarly, esters and lactones give enol ethers and acetylenes give vinylcyclopropanes.