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1-Bromoadamantane

Catalog No. A14893 Name Alfa Aesar
CAS Number 768-90-1 Website
M. F. C10H15Br Telephone
M. W. 215.1301 Fax
Purity 99% Email
Storage Chembase ID: 80001

SYNONYMS

Title
1-溴金刚烷
IUPAC name
1-bromoadamantane
IUPAC Traditional name
1-bromoadamantane
Synonyms
1-Adamantyl bromide

DATABASE IDS

MDL Number MFCD00074721
EC Number 212-200-7
CAS Number 768-90-1
Beilstein Number 1098857

PROPERTIES

Purity 99%
Melting Point 117-121°C
TSCA Listed

DETAILS

REFERENCES

  • Reduction with Tri-n-butyltin hydride, A13298, generates the 1-adamantyl radical which, e.g. adds to Michael acceptors in good yield: J. Org. Chem., 53, 1285 (1988).
  • With activated Ca metal (prepared from CaBr2 and Li biphenylide), forms an organocalcium reagent which reacts with ketones to give tertiary alcohols; the preparation and reactivity of these intermediates is discussed: Org. Synth. Coll., 9, 9 (1998).
  • Undergoes Heck-type coupling with styrenes and arenes, catalyzed by Pd on carbon: Synthesis, 148 (1998).