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O-Methylisourea hydrochloride_Molecular_structure_CAS_5329-33-9)
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O-Methylisourea hydrochloride

Catalog No. A14773 Name Alfa Aesar
CAS Number 5329-33-9 Website
M. F. C2H7ClN2O Telephone
M. W. 110.54278 Fax
Purity 98% Email
Storage Chembase ID: 295336

SYNONYMS

Title
O-甲基异脲盐酸盐
IUPAC name
methoxymethanimidamide hydrochloride
IUPAC Traditional name
methoxymethanimidamide hydrochloride

DATABASE IDS

Beilstein Number 3909619
MDL Number MFCD00035043
CAS Number 5329-33-9

PROPERTIES

Purity 98%
Melting Point ca 116°C dec.
GHS Pictograms GHS07
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
GHS Precautionary statements P261-P305+P351+P338-P302+P352-P321-P405-P501A
Risk Statements 36/37/38
Safety Statements 26-37
TSCA Listed

DETAILS

REFERENCES

  • Reagent for guanylation of primary and secondary amines: Chem.-Ztg., 98, 617 (1974).
  • Reagent for selective methylation of SH groups at pH 8.5: Biochemistry, 9, 3343 (1970); 11, 110 (1972).
  • For a review of the synthetic applications of isoureas, see: Org. Prep. Proced. Int., 12, 309 (1980).
  • Useful intermediate, more nucleophilic than urea itself, and avoiding toxicity of thiourea, in the synthesis of pyrimidines, by condensation with ?-diketones: Chem. Ber., 109, 3255 (1976); and of uracils, by condensation with ?-keto esters: Tetrahedron, 40, 3313 (1984); J. Heterocycl. Chem., 26, 883 (1989).