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trans-Cinnamaldehyde

Catalog No. A14689 Name Alfa Aesar
CAS Number 14371-10-9 Website
M. F. C9H8O Telephone
M. W. 132.15922 Fax
Purity 98+% Email
Storage Chembase ID: 92763

SYNONYMS

Title
反-肉桂醛
IUPAC name
(2E)-3-phenylprop-2-enal
IUPAC Traditional name
cinnamal
Synonyms
trans-3-Phenylacrolein

DATABASE IDS

Merck Index 142297
Beilstein Number 1071571
CAS Number 14371-10-9
MDL Number MFCD00007000

PROPERTIES

Purity 98+%
Boiling Point 250-252°C
Density 1.050
Flash Point 131°C(268°F)
Melting Point -8°C
Refractive Index 1.6220
GHS Pictograms GHS07
GHS Hazard statements H315-H319-H317-H303-H313
European Hazard Symbols Irritant Irritant (Xi)
GHS Precautionary statements P280G-P262-P305+P351+P338
Risk Statements 36/38-43
RTECS GD6475000
Safety Statements 24-26-37
Storage Warning Air Sensitive
TSCA Listed

DETAILS

REFERENCES

  • For reaction with 1,2-Ethanedithiol, L12865 to give the dithiolane, followed by coupling with trimethylsilylmethyl magnesium chloride, catalyzed by Dichlorobis(triphenylphosphine)nickel(II), 13930, as an example of Ni catalyzed coupling of dithioacetals with Grignards, see: J. Org. Chem., 53, 5582 (1988); Org. Synth. Coll., 9, 727 (1998):
  • For details of the 1,2-addition of a functionalized Zn-Cu organometallic RCu(CN)ZnI to give an allylic alcohol, see; Org. Synth. Coll., 9, 502 (1998).