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Hydrogen bromide

Catalog No. A14475 Name Alfa Aesar
CAS Number 10035-10-6 Website
M. F. BrH Telephone
M. W. 80.91194 Fax
Purity 33% w/w (45% w/v) soln. in acetic acid Email
Storage Chembase ID: 76437

SYNONYMS

Title
氢溴酸
IUPAC name
hydrogen bromide
IUPAC Traditional name
hydrogen bromide
Synonyms
Hydrobromic acid acetic acid solution

DATABASE IDS

Beilstein Number 3587158
Merck Index 144778
MDL Number MFCD00011323
CAS Number 10035-10-6
EC Number 233-113-0

PROPERTIES

Purity 33% w/w (45% w/v) soln. in acetic acid
Density 1.40
Flash Point 65°C(149°F)
GHS Pictograms GHS05
GHS Pictograms GHS06
GHS Hazard statements H331-H314-H318-H227
European Hazard Symbols Corrosive Corrosive (C)
GHS Precautionary statements P280-P305+P351+P338-P309-P310
Risk Statements 35
RTECS MW3850000
Safety Statements 26-36/37/39-45
TSCA Listed
Hazard Class 8
UN Number UN3265
Packing Group II

DETAILS

REFERENCES

  • Preferred reagent for the non-hydrogenolytic cleavage of the N-benzyloxycarbonyl (Cbz, Z) group in peptide synthesis: J. Org. Chem., 17, 1564 (1952). For peptide reagents, see Appendix 6.
  • Used in combination with Paraformaldehyde, A11313, or 1,3,5-Trioxane, A15639, for the bromomethylation of aromatics: J. Org. Chem., 58, 1262 (1993); Synlett, 55 (1989). For N-bromomethylation of phthalimide and other imides, see: Synlett, 933 (1994).
  • For use in the bromoacetoxylation of (S)-(+)-1,2-Propanediol, B21773, as an example of the conversion of chiral vic-diols to epoxides with retention of configuration, see: J. Chem. Soc., Perkin 1, 1214 (1973); Org. Synth. Coll., 7, 356 (1990).