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1,2-Cyclohexanedione

Catalog No. A14401 Name Alfa Aesar
CAS Number 765-87-7 Website
M. F. C6H8O2 Telephone
M. W. 112.12652 Fax
Purity 98+% Email
Storage Chembase ID: 73953

SYNONYMS

Title
1,2-环己二酮
IUPAC name
cyclohexane-1,2-dione
IUPAC Traditional name
1,2-cyclohexanedione
Synonyms
Dihydrocatechol

DATABASE IDS

Beilstein Number 507419
CAS Number 765-87-7
EC Number 212-155-3
MDL Number MFCD00001648

PROPERTIES

Purity 98+%
Boiling Point 193-195°C
Density 1.12
Flash Point 84°C(183°F)
Melting Point 35-38°C
Refractive Index 1.5190
RTECS GV0340000
TSCA Listed

DETAILS

REFERENCES

  • Protection of trans-1,2-diols as cyclic diacetals has been accomplished by Ley's group using the diketone in combination with trimethyl orthoformate and camphorsulfonic acid. The method is particularly applicable to the carbohydrate field: Synlett, 793 (1996):
  • See also Org. Synth., 75, 170 (1997), for an alternative method.
  • Undergoes copper-catalyzed oxidative cleavage to give 2-halo diacids: Synthesis, 917 (1992):