Allyl chloride

• Catalog No.: A14330
• CAS Number: 107-05-1
• M. F.: C3H5Cl
• M. W.: 76.5248
• Purity: 98%, stab. with propylene oxide

SYNONYMS

• Title: 烯丙基氯
• IUPAC name: 3-chloroprop-1-ene
• IUPAC Traditional name: allyl chloride
• Synonyms: 3-Chloro-1-propene

DATABASE IDS

• MDL Number: MFCD00000984
• EC Number: 203-457-6
• CAS Number: 107-05-1
• Beilstein Number: 635704
• Merck Index: 14289

PROPERTIES

• Purity: 98%, stab. with propylene oxide
• Boiling Point: 44-46°C
• Density: 0.939
• Flash Point: -28°C(-18°F)
• Melting Point: -135°C
• Refractive Index: 1.4160
• GHS Hazard statements: H225-H341-H351-H373-H400-H302-H312-H332-H315-H319-H335
• European Hazard Symbols: X
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Nature polluting (N)
• GHS Precautionary statements: P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
• Risk Statements: 11-20/21/22-36/37/38-40-48/20-68-50
• RTECS: UC7350000
• Safety Statements: 2-16-25-26-36/37-46-61
• TSCA Listed: 是
• Hazard Class: 3
• UN Number: UN1100
• Packing Group: I

REFERENCES

• Lithiation with LDA in THF at -78^o generatesɑ-chloroallyllithium which can be ɑ-alkylated with primary bromides in high yield. Displacement of the resulting allylic chloride with a dialkyl cuprate to give, stereoselectively, an (E)-alkene, has been used in a pheromone synthesis: J. Org. Chem., 45, 1504 (1981).
• Treatment with sodium bis(trimethylsilyl)amide gives the strained, highly reactive alkene cyclopropene. For details and Diels-Alder reactions, see: J. Org. Chem., 61, 6462 (1996).