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1,3,5-Trimethoxybenzene

Catalog No. A13981 Name Alfa Aesar
CAS Number 621-23-8 Website
M. F. C9H12O3 Telephone
M. W. 168.18978 Fax
Purity 99% Email
Storage Chembase ID: 78368

SYNONYMS

Title
1,3,5-三甲氧基苯
IUPAC name
1,3,5-trimethoxybenzene
IUPAC Traditional name
1,3,5-trimethoxybenzene
Synonyms
Phloroglucinol trimethyl ether

DATABASE IDS

Beilstein Number 1307993
EC Number 210-673-4
MDL Number MFCD00008385
CAS Number 621-23-8

PROPERTIES

Purity 99%
Boiling Point 255°C
Flash Point 85°C(185°F)
Melting Point 51-53°C
GHS Pictograms GHS06
GHS Hazard statements H301
European Hazard Symbols X
GHS Precautionary statements P264-P270-P301+P310-P321-P405-P501A
Risk Statements 22
RTECS DC2810000
Safety Statements 36
TSCA Listed

DETAILS

REFERENCES

  • Direct dilithiation with n-BuLi/TMEDA gave, after reaction with TMS chloride, the 2,4-disilyl derivative in 85-95% yield: J. Org. Chem., 49, 4657 (1984).
  • Has been used as the non-transferable group in the conjugate addition of organocuprates. (With Li dialkyl cuprates only one of the two alkyl groups is transferred, with consequent 50% maximum yield.): Chem. Lett., 745 (1988):