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Biphenyl-4-carbonyl chloride_Molecular_structure_CAS_14002-51-8)
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Biphenyl-4-carbonyl chloride

Catalog No. A13956 Name Alfa Aesar
CAS Number 14002-51-8 Website
M. F. C13H9ClO Telephone
M. W. 216.66296 Fax
Purity 98% Email
Storage Chembase ID: 88259

SYNONYMS

Title
联苯-4-甲酰氯
IUPAC name
4-phenylbenzoyl chloride
IUPAC Traditional name
4-phenylbenzoyl chloride
Synonyms
4-Phenylbenzoyl chloride

DATABASE IDS

CAS Number 14002-51-8
MDL Number MFCD00000692
EC Number 237-804-8
Beilstein Number 472842

PROPERTIES

Purity 98%
Boiling Point 160°C/2mm
Melting Point 110-115°C
GHS Pictograms GHS05
GHS Hazard statements H314-H318
European Hazard Symbols Corrosive Corrosive (C)
GHS Precautionary statements P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A
Risk Statements 34
Safety Statements 26-36/37/39-45
Storage Warning Moisture Sensitive
TSCA Listed
Hazard Class 8
UN Number UN3261
Packing Group II

DETAILS

REFERENCES

  • Protection of the OH group of a non-crystalline prostaglandin intermediate, in the presence of pyridine, enabled isolation as the crystalline 4-phenylbenzoate ester: J. Am. Chem. Soc., 93, 1491 (1971). For protection of 3-azido-2,3-dideoxypentoses in a short AZT synthesis, see: Synthesis, 451 (1991). Again, the solid nature of these intermediates facilitates isolation.
  • Protection of amines as their crystalline 4-phenylbenzamides has also been recommended. These amides can be cleaved with sodium amalgam: Tetrahedron Lett., 3853 (1976).