Iodoform

• Catalog No.: A13664
• CAS Number: 75-47-8
• M. F.: CHI3
• M. W.: 393.73205
• Purity: 99%

SYNONYMS

• Title: 碘仿
• IUPAC name: triiodomethane
• IUPAC Traditional name: iodoform
• Synonyms: Triiodomethane

DATABASE IDS

• Merck Index: 145033
• Beilstein Number: 1697010
• MDL Number: MFCD00001069
• CAS Number: 75-47-8
• EC Number: 200-874-5

PROPERTIES

• Purity: 99%
• Density: 4.008
• Flash Point: None
• Melting Point: 118-123°C
• GHS Hazard statements: H301-H311-H332-H315-H319-H335
• European Hazard Symbols: X
• GHS Precautionary statements: P261-P301+P310-P305+P351+P338-P361-P405-P501A
• Risk Statements: 20/21/22-36/37/38
• RTECS: PB7000000
• Safety Statements: 26-36/37
• Storage Warning: Light Sensitive
• TSCA Listed: 是

REFERENCES

• Precursor of diiodocarbene under phase-transfer conditions: Angew. Chem. Int. Ed., 13, 132 (1974), or using KO-t-Bu: Synthesis, 313 (1976). Generation of diiodocarbene with NaH in ether and reaction with malonate is the first step of a route to vinyl iodides: J. Chem. Soc., Perkin 1, 47 (1990):
  
• In the presence of solid NaOH, free radical iodination of saturated hydrocarbons has been accomplished under mild conditions. The reaction is thought to involve the triiodomethyl radical as a chain carrier: Angew. Chem. Int. Ed., 38, 2786 (1999).