Diethyl phenylthiomethylphosphonate

• Catalog No.: A13660
• CAS Number: 38066-16-9
• M. F.: C11H17O3PS
• M. W.: 260.289641
• Purity: 96%

SYNONYMS

• Title: 苯硫甲基磷酸二乙酯
• IUPAC name: diethyl [(phenylsulfanyl)methyl]phosphonate
• IUPAC Traditional name: diethyl (phenylsulfanyl)methylphosphonate
• Synonyms: Phenylthiomethylphosphonic acid diethyl ester

DATABASE IDS

• Beilstein Number: 1246215
• CAS Number: 38066-16-9
• EC Number: 253-770-7
• MDL Number: MFCD00015130

PROPERTIES

• Purity: 96%
• Boiling Point: 146-148°C/0.5mm
• Density: 1.174
• Refractive Index: 1.5340
• Safety Statements: 24/25
• TSCA Listed: 否

REFERENCES

• Horner-Wadsworth-Emmons olefination (see Appendix 1) with carbonyl compounds gives enol thioethers, convertible to aldehydes: J. Chem. Soc., 1324 (1963). Compare Diethyl methylthiomethylphosphonate, L00579.
• For use in a synthesis of vinylphosphonates, in which the double bond is introduced by sulfoxide elimination, see: Synthesis, 917 (1982):