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1-Bromo-3-methyl-2-butene

Catalog No. A13388 Name Alfa Aesar
CAS Number 870-63-3 Website
M. F. C5H9Br Telephone
M. W. 149.02896 Fax
Purity 90+%, stab. with silver Email
Storage Chembase ID: 89100

SYNONYMS

Title
1-溴-3-甲基-2-丁烯
IUPAC name
1-bromo-3-methylbut-2-ene
IUPAC Traditional name
1-bromo-3-methylbut-2-ene
Synonyms
3,3-Dimethylallyl bromide
Prenyl bromide

DATABASE IDS

EC Number 212-799-5
MDL Number MFCD00000242
Beilstein Number 1420778
CAS Number 870-63-3

PROPERTIES

Hazard Class 8
UN Number UN2920
Packing Group II
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Hazard statements H314-H318-H226
European Hazard Symbols Corrosive Corrosive (C)
GHS Precautionary statements P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
Risk Statements 10-34
Safety Statements 26-36/37/39-45
Storage Warning Light Sensitive
TSCA Listed
Purity 90+%, stab. with silver
Boiling Point 135°C
Density 1.281
Flash Point 32°C(90°F)
Refractive Index 1.4895

DETAILS

REFERENCES

  • 3,3-Dimethylallyl (prenyl) building block group, useful in terpene synthesis. For use as an alkylating agent, see, e.g.: Org. Synth. Coll., 8, 381 (1993).
  • In the presence of the hindered base lithium 2,2,6,6-tetramethylpiperidide (LTMP) forms a carbenoid species which reacts with alkenes to provide vinylcyclopropenes: Synlett, 647 (1991):