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2-Benzoylbenzoic acid

Catalog No. A13281 Name Alfa Aesar
CAS Number 85-52-9 Website
M. F. C14H10O3 Telephone
M. W. 226.2274 Fax
Purity 98+% Email
Storage Chembase ID: 110009

SYNONYMS

Title
2-苯甲酰苯甲酸
IUPAC name
2-benzoylbenzoic acid
IUPAC Traditional name
2-benzoylbenzoic acid
Synonyms
Benzophenone-2-carboxylic acid
2-Carboxybenzophenone

DATABASE IDS

CAS Number 85-52-9
EC Number 201-612-2
MDL Number MFCD00002472
Beilstein Number 1107841

PROPERTIES

Purity 98+%
Boiling Point 257°C
Melting Point 127-130°C
GHS Pictograms GHS07
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
GHS Precautionary statements P280G-P305+P351+P338
Risk Statements 36/37/38
RTECS DG3600000
Safety Statements 26-37
TSCA Listed

DETAILS

REFERENCES

  • Primary and secondary alcohols can be protected as photolabile 2-benzoylbenzoate esters. Esterification can be accomplished in the presence of DCC/DMAP, and the ester is cleaved by photolysis in the presence of a reducing agent such as isopropanol or an amine, in which case the by-product is 3-phenylphthalide. The method has also been applied to the protection of thiols: J. Org. Chem., 61, 9455 (1996).