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1-Acetylferrocene

Catalog No. A13078 Name Alfa Aesar
CAS Number 1271-55-2 Website
M. F. C12H12FeO Telephone
M. W. 228.06808 Fax
Purity 97% Email
Storage Chembase ID: 295273

SYNONYMS

Title
1-乙酰基二茂铁
IUPAC name
(2-acetylcyclopenta-2,4-dien-1-yl)(cyclopenta-2,4-dien-1-yl)iron
IUPAC Traditional name
1-acetylferrocene
Synonyms
(Acetylcyclopentadienyl)cyclopentadienyliron
Ferrocenyl methyl ketone

DATABASE IDS

EC Number 215-043-2
MDL Number MFCD00001432
CAS Number 1271-55-2

PROPERTIES

Purity 97%
Boiling Point 160-163°C/4mm
Melting Point 79-86°C
GHS Pictograms GHS06
GHS Hazard statements H300-H310
European Hazard Symbols Highly toxic Highly toxic (T+)
GHS Precautionary statements P280-P301+P310-P361-P302+P350-P405-P501A
Risk Statements 24-28
RTECS OB3700000
Safety Statements 20-27/28-36/37-45-60
TSCA Listed
Hazard Class 6.1
UN Number UN3467
Packing Group II

DETAILS

REFERENCES

  • A procedure for the conversion of methyl ketones to terminal acetylenes is exemplified by reaction with POCl3 - DMF to give (2-formyl-1-chlorovinyl)ferrocene which, by elimination with NaOH, affords ethynylferrocene: J. Organomet. Chem., 6, 173 (1966); Org. Synth. Coll., 9, 411 (1998).