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Phenyl chloroformate

Catalog No. A12618 Name Alfa Aesar
CAS Number 1885-14-9 Website
M. F. C7H5ClO2 Telephone
M. W. 156.5664 Fax
Purity 99% Email
Storage Chembase ID: 92298

SYNONYMS

Title
氯甲酸苯酯
IUPAC name
phenyl chloroformate
IUPAC Traditional name
phenyl chloroformate
Synonyms
Chloroformic acid phenyl ester

DATABASE IDS

MDL Number MFCD00000637
Beilstein Number 606778
CAS Number 1885-14-9
EC Number 217-547-8

PROPERTIES

Purity 99%
Boiling Point 188-189°C
Density 1.246
Flash Point 76°C(169°F)
Melting Point -38°C
Refractive Index 1.5110
GHS Pictograms GHS05
GHS Pictograms GHS06
GHS Hazard statements H301-H330-H317-H314-H318-H227
European Hazard Symbols Highly toxic Highly toxic (T+)
GHS Precautionary statements P210-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P405-P501A
Risk Statements 22-26-34-43
RTECS FG3850000
Safety Statements 26-28-36/37/39-45
Storage Warning Moisture Sensitive
TSCA Listed
Hazard Class 6.1
UN Number UN2746
Packing Group II

DETAILS

REFERENCES

  • Precursor of phenyl mixed anhydrides, which can be used, e.g. in peptide coupling reactions.
  • Also used in the cleavage of tertiary amines: J. Chem. Soc. (C), 2015 (1967); cf Ethyl chloroformate, L06311, and 1-Chloroethyl chloroformate, L14197. Review: Synthesis, 1 (1989).
  • Reagent for dehydration of primary amides to nitriles under mild conditions: Indian J. Chem., 40B, 722 (2001).