Hexaethyl phosphorous triamide

• Catalog No.: A12490
• CAS Number: 2283-11-6
• M. F.: C12H30N3P
• M. W.: 247.360461
• Purity: 97%

SYNONYMS

• Title: 三(二乙氨基)膦
• IUPAC name: [bis(diethylamino)phosphanyl]diethylamine
• IUPAC Traditional name: [bis(diethylamino)phosphanyl]diethylamine
• Synonyms: Tris(diethylamino)phosphine

DATABASE IDS

• MDL Number: MFCD00009041
• CAS Number: 2283-11-6
• Beilstein Number: 636187
• EC Number: 218-920-8

PROPERTIES

• Purity: 97%
• Boiling Point: 245-246°C
• Density: 0.903
• Flash Point: 58°C(136°F)
• Refractive Index: 1.4737
• GHS Hazard statements: H226-H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• GHS Precautionary statements: P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
• Risk Statements: 36/37/38
• Safety Statements: 23-26-37
• Storage Warning: Air Sensitive
• TSCA Listed: 是
• Hazard Class: 3
• UN Number: UN1993
• Packing Group: III

REFERENCES

• Reducing agent, compare Hexamethylphosphorous triamide, A12571.
• For use in the Barton syntheses of hindered alkenes, involving desulfurization of small-ring heterocycles with elimination of nitrogen or carbon dioxide, see: Chem. Commun., 1225, 1226 (1970):
  
• Reagent for selective vicinal dehalogenation of halogenated alkanes to give perhalogenated alkenes. The method has potential for the synthesis of highly fluorinated and mixed fluoro-halo alkenes: J. Org. Chem., 57, 5018 (1992).