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2',4'-Dihydroxyacetophenone_Molecular_structure_CAS_89-84-9)
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2',4'-Dihydroxyacetophenone

Catalog No. A12066 Name Alfa Aesar
CAS Number 89-84-9 Website
M. F. C8H8O3 Telephone
M. W. 152.14732 Fax
Purity 98% Email
Storage Chembase ID: 75298

SYNONYMS

Title
2',4'-二羟基苯乙酮
IUPAC name
1-(2,4-dihydroxyphenyl)ethan-1-one
IUPAC Traditional name
2',4'-dihydroxyacetophenone
Synonyms
Resacetophenone
4-Acetylresorcinol

DATABASE IDS

MDL Number MFCD00002279
Beilstein Number 1282505
EC Number 201-945-3
CAS Number 89-84-9
Merck Index 148140

PROPERTIES

Purity 98%
Melting Point 142-146°C
GHS Pictograms GHS05
GHS Pictograms GHS07
GHS Hazard statements H318-H315-H335-H303
European Hazard Symbols Irritant Irritant (Xi)
GHS Precautionary statements P261-P305+P351+P338-P302+P352-P321-P405-P501A
Risk Statements 37/38-41
RTECS AM7525000
Safety Statements 26-37/39
Storage Warning Moisture Sensitive
TSCA Listed

DETAILS

REFERENCES

  • The position of O-alkylation can be varied by suitable choice of reagent. Thus, NaH in DMSO followed by MeI gives predominantly the 2-alkylated product, whereas Li2CO3 in DMF favors 4-alkylation. The latter is a fairly general method for the alkylation of phenols, thiophenols and ?-diketones with pKa less than about 8: Synth. Commun., 18, 1379 (1988).