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4-Bromoanisole

Catalog No. A11824 Name Alfa Aesar
CAS Number 104-92-7 Website
M. F. C7H7BrO Telephone
M. W. 187.03388 Fax
Purity 99% Email
Storage Chembase ID: 70412

SYNONYMS

Title
4-溴苯甲醚
IUPAC name
1-bromo-4-methoxybenzene
IUPAC Traditional name
bromoanisole
Synonyms
4-Methoxybromobenzene

DATABASE IDS

EC Number 203-252-1
Beilstein Number 1237590
MDL Number MFCD00000097
Merck Index 141427
CAS Number 104-92-7

PROPERTIES

Purity 99%
Boiling Point 98-99°C/10mm
Density 1.494
Flash Point 94°C(201°F)
Melting Point 10-13°C
Refractive Index 1.5640
GHS Hazard statements H303
GHS Precautionary statements P312
RTECS BZ8501000
TSCA Listed

DETAILS

REFERENCES

  • For formation of the Grignard, conversion to the stannane and Stille coupling with an aryl triflate, catalyzed by trans-Dichlorobis(triphenylphosphine)palladium(II), 10491, see: Org. Synth. Coll., 9, 553 (1998).
  • Nucleophilic displacement of Br can be effected with Na alkoxides in NMP in the presence of CuBr: Tetrahedron, 48, 3633 (1992).