Diethylamine

• Catalog No.: A11716
• CAS Number: 109-89-7
• M. F.: C4H11N
• M. W.: 73.13684
• Purity: 99+%

SYNONYMS

• Title: 二乙胺
• IUPAC name: diethylamine
• IUPAC Traditional name: diethylamine

DATABASE IDS

• MDL Number: MFCD00009032
• CAS Number: 109-89-7
• Beilstein Number: 605268
• EC Number: 203-716-3
• Merck Index: 143111

PROPERTIES

• Purity: 99+%
• Boiling Point: 54-55°C
• Density: 0.706
• Flash Point: -28°C(-18°F)
• Melting Point: -50°C
• Refractive Index: 1.3860
• GHS Hazard statements: H225-H314-H302-H312-H332
• European Hazard Symbols: X
• European Hazard Symbols: Corrosive (C)
• European Hazard Symbols: Flammable (F)
• GHS Precautionary statements: P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
• Risk Statements: 11-20/21/22-35
• RTECS: HZ8750000
• Safety Statements: 3-16-26-29-36/37/39-45
• Storage Warning: Air Sensitive
• TSCA Listed: 是
• Hazard Class: 3
• UN Number: UN1154
• Packing Group: II

REFERENCES

• Alkali metal diethylamides, generated with n-BuLi or NaH, have been used for the cleavage of ethers: J. Organomet. Chem., 55, 41 (1973); Synthesis, 638 (1980), and of alkyl aryl sulfides, for which HBr and HI are usually poor: Synthesis, 583 (1982).
• In combination with Lithium aluminum hydride, A18116, generates lithium tris(diethylamino)aluminum hydride, which is a useful selective reducing agent, for example: esters to aldehydes: J. Org. Chem., 52, 5486 (1987); amides to aldehydes: Tetrahedron Lett., 32, 6903 (1991).