3,5-Bis(trifluoromethyl)benzeneboronic acid

• Catalog No.: A11373
• CAS Number: 73852-19-4
• M. F.: C8H5BF6O2
• M. W.: 257.9255192
• Purity: 97+%

SYNONYMS

• Title: 3,5-双(三氟甲基)苯硼酸
• IUPAC name: [3,5-bis(trifluoromethyl)phenyl]boronic acid
• IUPAC Traditional name: 3,5-bis(trifluoromethyl)phenylboronic acid
• Synonyms: 3,5-Bis(trifluoromethyl)phenylboronic acid

DATABASE IDS

• EC Number: 000-000-0
• Beilstein Number: 7379990
• CAS Number: 73852-19-4
• MDL Number: MFCD00051850

PROPERTIES

• Purity: 97+%
• Melting Point: 219-224°C
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• GHS Precautionary statements: P261-P305+P351+P338-P302+P352-P321-P405-P501A
• Risk Statements: 36/37/38
• Safety Statements: 26-37
• TSCA Listed: 否

REFERENCES

• Has been used to form chiral catalysts for use in enantioselective Diels-Alder reactions; see, for example: J. Org. Chem., 62, 3026 (1997) and references therein. See Appendix 5.
• GC reagent for diols: J. Chromat., 158, 33 (1978); 186, 307 (1979).
• Has been used to protect a 1,3-diamine as the 2-aryl-1,3,2-diazaborinane, permitting selective reaction at a remote amine function: J. Am. Chem. Soc., 118, 1569 (1996).