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3-Bromocyclohexene

Catalog No. A10370 Name Alfa Aesar
CAS Number 1521-51-3 Website
M. F. C6H9Br Telephone
M. W. 161.03966 Fax
Purity 95%, stab. with 300-1000ppm Propylene oxide Email
Storage Chembase ID: 111735

SYNONYMS

Title
3-溴环己烯
IUPAC name
3-bromocyclohex-1-ene
IUPAC Traditional name
3-bromocyclohex-1-ene
Synonyms
2-Cyclohexenyl bromide

DATABASE IDS

CAS Number 1521-51-3
Beilstein Number 635953
MDL Number MFCD00013775

PROPERTIES

Purity 95%, stab. with 300-1000ppm Propylene oxide
Boiling Point 64-65°C/15mm
Density 1.400
Flash Point 54°C(129°F)
Refractive Index 1.5310
GHS Pictograms GHS02
GHS Pictograms GHS07
GHS Hazard statements H226-H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
GHS Precautionary statements P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
Risk Statements 10-36/37/38
Safety Statements 26-37
TSCA Listed
Hazard Class 3
UN Number UN1993
Packing Group III

DETAILS

REFERENCES

  • In peptide synthesis, can be used to protect the hydroxyl group of serine and threonine as the cyclohexyl (Chx) ether, by reaction with the sodium alkoxide (generated with NaH), followed by hydrogenation. The group is stable to TFA and 20% piperidine in DMF, but can be cleaved with TfOH in TFA, in the presence of thioanisole as a cation scavenger: J. Chem. Soc., Perkin 1, 1949 (2000). See Appendix 6.