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Dimethylaminoacetonitrile

Catalog No. B25085 Name Alfa Aesar
CAS Number 926-64-7 Website
M. F. C4H8N2 Telephone
M. W. 84.11972 Fax
Purity 98% Email
Storage Chembase ID: 108350

SYNONYMS

Title
二甲氨基乙腈
IUPAC name
2-(dimethylamino)acetonitrile
IUPAC Traditional name
acetonitrile, (dimethylamino)

DATABASE IDS

Beilstein Number 1735677
EC Number 213-140-4
MDL Number MFCD00001890
CAS Number 926-64-7

PROPERTIES

Purity 98%
Boiling Point 137-138°C
Density 0.863
Flash Point 36°C(96°F)
Refractive Index 1.4100
GHS Pictograms GHS02
GHS Pictograms GHS06
GHS Hazard statements H300-H310-H319-H226
European Hazard Symbols Highly toxic Highly toxic (T+)
GHS Precautionary statements P260-P280H-P305+P351+P338-P302+P352-P309-P310
Risk Statements 10-25-27-36
RTECS AL9450000
Safety Statements 23-26-28-36/37-45
TSCA Listed
Hazard Class 3
UN Number UN2378
Packing Group II

DETAILS

REFERENCES

  • Formyl anion equivalent. Self-condensation was found to compete with alkylation in the Stork LDA procedure, but the molecule was successfully used to introduce a formyl group by SN2' alkylation in the presence of K2CO3, in a synthesis of -cyclocitral: Tetrahedron Lett., 25, 3457 (1984):
  • For a review of the use of ɑ-dialkylaminonitriles as acyl anion equivalents, see: Tetrahedron, 39, 3207 (1983).