Dimethylaminoacetonitrile

• Catalog No.: B25085
• CAS Number: 926-64-7
• M. F.: C4H8N2
• M. W.: 84.11972
• Purity: 98%

SYNONYMS

• Title: 二甲氨基乙腈
• IUPAC name: 2-(dimethylamino)acetonitrile
• IUPAC Traditional name: acetonitrile, (dimethylamino)

DATABASE IDS

• Beilstein Number: 1735677
• EC Number: 213-140-4
• MDL Number: MFCD00001890
• CAS Number: 926-64-7

PROPERTIES

• Purity: 98%
• Boiling Point: 137-138°C
• Density: 0.863
• Flash Point: 36°C(96°F)
• Refractive Index: 1.4100
• GHS Hazard statements: H300-H310-H319-H226
• European Hazard Symbols: Highly toxic (T+)
• GHS Precautionary statements: P260-P280H-P305+P351+P338-P302+P352-P309-P310
• Risk Statements: 10-25-27-36
• RTECS: AL9450000
• Safety Statements: 23-26-28-36/37-45
• TSCA Listed: 否
• Hazard Class: 3
• UN Number: UN2378
• Packing Group: II

REFERENCES

• Formyl anion equivalent. Self-condensation was found to compete with alkylation in the Stork LDA procedure, but the molecule was successfully used to introduce a formyl group by S_N2' alkylation in the presence of K₂CO₃, in a synthesis of -cyclocitral: Tetrahedron Lett., 25, 3457 (1984):
  
• For a review of the use of ɑ-dialkylaminonitriles as acyl anion equivalents, see: Tetrahedron, 39, 3207 (1983).