Methyl 2,3:4,6-Di-O-benzylidene-α-D-mannopryanoside

• Catalog No.: M300110
• CAS Number: 4148-71-4
• M. F.: C21H22O6
• M. W.: 370.39578
• Storage: Refrigerator

SYNONYMS

• IUPAC name: (1R,2S,4S,7S,9R,12R)-7-methoxy-4,12-diphenyl-3,5,8,11,13-pentaoxatricyclo[7.4.0.0^2,^6]tridecane
• IUPAC Traditional name: (1R,2S,4S,7S,9R,12R)-7-methoxy-4,12-diphenyl-3,5,8,11,13-pentaoxatricyclo[7.4.0.0^2,^6]tridecane
• Synonyms: NSC 266498; Methyl 2,3:4,6-Bis-O-(phenylmethylene)-α-D-mannopyranoside

DATABASE IDS

• CAS Number: 4148-71-4

PROPERTIES

• Apperance: White Crystalline Solid
• Melting Point: 182-184°C
• Storage Condition: Refrigerator

DETAILS

Description (English)

Methyl 2,3:4,6-Di-O-benzylidene-α-D-mannopryanoside is used in the synthesis of a key intermediate of (+)-ajmalicine from carbohydrates and tryptamine.

REFERENCES

• Horton, D., et al.: Carbohydr. Res., 44, 227 (1975)