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Ethyl 2,3-Di-O-benzyl-4,6-O-benzylidene-1-deoxy-1-thio-α-D-mannopyranoside S-Oxide_Molecular_structure_CAS_188357-34-8)
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Ethyl 2,3-Di-O-benzyl-4,6-O-benzylidene-1-deoxy-1-thio-α-D-mannopyranoside S-Oxide

Catalog No. E915775 Name Toronto Research Chemicals
CAS Number 188357-34-8 Website http://www.trc-canada.com
M. F. C29H32O6S Telephone +1 (416) 665-9696
M. W. 508.62578 Fax +1 (416) 665-4439
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Storage Chembase ID: 168494

SYNONYMS

IUPAC name
(4aR,6R,7S,8S,8aR)-7,8-bis(benzyloxy)-6-(ethanesulfinyl)-2-phenyl-hexahydro-2H-pyrano[3,2-d][1,3]dioxine
IUPAC Traditional name
(4aR,6R,7S,8S,8aR)-7,8-bis(benzyloxy)-6-(ethanesulfinyl)-2-phenyl-hexahydro-2H-pyrano[3,2-d][1,3]dioxine
Synonyms
1-Deoxy-1-(ethylsulfinyl)-2,3-bis-O-(phenylmethyl)-4,6-O-[(R)-phenylmethylene]-α-D-mannopyranose

DATABASE IDS

CAS Number 188357-34-8

PROPERTIES

Certificate of Analysis Download
Apperance White Solid
Melting Point 123-124°C
Solubility Dichloromethane
Solubility Ethyl Acetate
MSDS Link Download

DETAILS

Description (English)
Used in direct synthesis of β-mannopyranosides by the sulfoxide method.

REFERENCES

  • Srivastava, V., et al.: Carbohydr. Res., 79, C13 (1980)
  • Liang, R., et al.: Science, 274, 1520 (1980)