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1,6-Anhydro-2,3,4-tri-O-benzyl-β-D-glucopyranose_Molecular_structure_CAS_10548-46-6)
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1,6-Anhydro-2,3,4-tri-O-benzyl-β-D-glucopyranose

Catalog No. A658750 Name Toronto Research Chemicals
CAS Number 10548-46-6 Website http://www.trc-canada.com
M. F. C27H28O5 Telephone +1 (416) 665-9696
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Storage -20°C Freezer Chembase ID: 160699

SYNONYMS

IUPAC name
(1R,2R,3S,4R,5R)-2,3,4-tris(benzyloxy)-6,8-dioxabicyclo[3.2.1]octane
IUPAC Traditional name
(1R,2R,3S,4R,5R)-2,3,4-tris(benzyloxy)-6,8-dioxabicyclo[3.2.1]octane
Synonyms
1,6-Anhydro-2,3,4-tris-O-(phenylmethyl)-β-D-glucopyranose
Tri-O-benzyllevoglucosan

DATABASE IDS

CAS Number 10548-46-6

PROPERTIES

Certificate of Analysis Download
Apperance Off-White Solid
Melting Point 81-84°C
Solubility Chloroform
Solubility Ethyl Acetate
MSDS Link Download
Storage Condition -20°C Freezer

DETAILS

Description (English)
1,6-Anhydrohexopyranoses have proven to be valuable synthons for the preparation of biologically important and structurally diverse products (e.g. rifamycin S, indanomycin, thromboxane B2, (+)-biotin, tetrodotoxin, quinone, and macrolide antibiotics) as

REFERENCES

  • Fraser-Reid, B., et al. J. Am. Chem. Soc. 106, 731 (1984)
  • Edwards, M.P., et al. J. Org. Chem. 49, 3503 (1984)
  • Kelly, A.G., and Roberts, J.S. J. Chem. Soc., Chem. Commun. 228, (1984)
  • Ogawa, T., et al. Carbohydr. Res. 57, C31 (1984)
  • Isobe, M., et al. Te