Home > Compound List > Product Information
Diisobutylaluminum hydride solution_Molecular_structure_CAS_1191-15-7)
Click picture or here to close

Diisobutylaluminum hydride solution

Catalog No. 38150 Name Sigma Aldrich
CAS Number 1191-15-7 Website http://www.sigmaaldrich.com
M. F. C8H19Al Telephone 1-800-521-8956
M. W. 142.217998 Fax
Purity Email
Storage Chembase ID: 127050

SYNONYMS

Title
二异丁基氢化铝 溶液
IUPAC name
bis(2-methylpropyl)alumane
IUPAC Traditional name
diisobutylaluminium hydride
Synonyms
DIBAL-H
DIBAL

DATABASE IDS

CAS Number 1191-15-7
MDL Number MFCD00008928
Beilstein Number 4123663

PROPERTIES

Concentration 0.7-1.3 M in methylene chloride
Grade purum
Linear Formula [(CH3)2CHCH2]2AlH
Density 1.22 g/mL at 20 °C
Flash Point -17 °C
Flash Point 1.4 °F
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Pictograms GHS08
GHS Signal Word Danger
GHS Hazard statements H225-H250-H261-H314-H351
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P210-P222-P231 + P232-P280-P305 + P351 + P338-P422
RID/ADR UN 3394 4.2/PG 1
Risk Statements 11-14/15-17-34-40
Safety Statements 16-26-36/37/39-43-45
German water hazard class 2

DETAILS

Description (English)
Application
Used in Pd-catalyzed reductive debromination of secondary alkyl bromides.1 O-Debenzylation and ring opening of perbenzylated furanosides.2 Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H.3
reducing agent
Description (简体中文)
Application
Used in Pd-catalyzed reductive debromination of secondary alkyl bromides.1 O-Debenzylation and ring opening of perbenzylated furanosides.2 Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H.3
还原剂

REFERENCES