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Manganese(II) chloride monohydrate

Catalog No. 13220 Name Sigma Aldrich
CAS Number 64333-01-3 Website http://www.sigmaaldrich.com
M. F. Cl2H2MnO Telephone 1-800-521-8956
M. W. 143.859329 Fax
Purity ≥97.0% Email
Storage Chembase ID: 139907

SYNONYMS

Title
氯化亚锰 一水合物
IUPAC name
dichloromanganese hydrate
IUPAC Traditional name
manganese(II) chloride hydrate
Synonyms
Manganese dichloride monohydrate

DATABASE IDS

PubChem SID 24847553
MDL Number MFCD00149793
CAS Number 64333-01-3
EC Number 231-869-6

PROPERTIES

GHS Hazard statements H302
European Hazard Symbols Harmful Harmful (Xn)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Risk Statements 22-52
Safety Statements 22-36-61
German water hazard class 1
GHS Pictograms GHS07
GHS Signal Word Warning
Antion Traces sulfate (SO42-): ≤1000 mg/kg
Cation Traces Fe: ≤200 mg/kg
Impurities ≤0.01% heavy metals (as Pb)
Linear Formula MnCl2 · H2O
Purity ≥97.0%

DETAILS

Description (English)
Application
Starting material for preparation of organomanganese chloride reagents; in combination with RLi or RMgX catalyzes reduction of vinyl and aryl halides, stereoselective coupling of vinyl iodides, and alkylation of enol triflates; also used for Mn-Cu-catalyzed conjugate addition of RMgX to enones and for Mn-catalyzed acylation of RMgX by acyl chlorides; in combination with NaBH4 is diastereoselective reducing agent; starting material for the preparation of Mn enolates regio- andstereo-selectively.
Description (简体中文)
Application
Starting material for preparation of organomanganese chloride reagents; in combination with RLi or RMgX catalyzes reduction of vinyl and aryl halides, stereoselective coupling of vinyl iodides, and alkylation of enol triflates; also used for Mn-Cu-catalyzed conjugate addition of RMgX to enones and for Mn-catalyzed acylation of RMgX by acyl chlorides; in combination with NaBH4 is diastereoselective reducing agent; starting material for the preparation of Mn enolates regio- andstereo-selectively.

REFERENCES