Sodium methoxide solution

• Catalog No.: 156256
• CAS Number: 124-41-4
• M. F.: CH3NaO
• M. W.: 54.02369

SYNONYMS

• Title: 甲醇钠 溶液
• IUPAC name: sodium methanolate
• IUPAC Traditional name: sodium methoxide
• Synonyms: 甲氧基钠; sodium methylate

DATABASE IDS

• PubChem SID: 24849600
• CAS Number: 124-41-4
• MDL Number: MFCD00012179
• Beilstein Number: 3592982

PROPERTIES

• Concentration: 25 wt. % in methanol
• Linear Formula: CH3ONa
• Auto Ignition Point: 878 °F
• Density: 0.945 g/mL at 25 °C
• Flash Point: 11 °C
• Flash Point: 51.8 °F
• Refractive Index: n20/D 1.37
• Vapor Density: 1.1 (vs air)
• Vapor Pressure: 50 mmHg ( 20 °C)
• Vapor Pressure: 96 mmHg ( 25 °C)
• GHS Signal Word: Danger
• GHS Hazard statements: H225-H251-H301 + H311 + H331-H314-H370
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Toxic (T)
• GHS Precautionary statements: P210-P235 + P410-P260-P280-P301 + P310-P305 + P351 + P338
• RID/ADR: UN 1289 3/PG 2
• Risk Statements: 11-14-23/24/25-34-39/23/24/25
• Safety Statements: 16-26-36/37/39-45
• Supplemental Hazard Statements: Reacts violently with water.
• Hazard Class: 3
• UN Number: 1289
• Packing Group: 2
• German water hazard class: 1

DETAILS

Description (English)

Packaging
1, 2, 2.5 L in glass bottle
18 L in steel drum
25 mL in glass bottle
Application
A novel high-spin hexanuclear Mn(III) cluster, [NaMn6(OMe)12(dbm)6]+, was synthesized via MnCl2 oxidation with simultaneous NaOMe promoted aggregation. This cluster has an unprecedented cyclic structure and 24 unpaired electrons in its ground state.1

Description (简体中文)

包装
1, 2, 2.5 L in glass bottle
18 L in steel drum
25 mL in glass bottle
Application
通过 MnCl2 氧化及同时进行的 NaOMe 促进型聚集来合成一种新型高自旋六核 Mn(III) 原子簇化合物 [NaMn6(OMe)12(dbm)6]+。该原子簇化合物具有全新的环状结构，在基态时具有 24 个不成对电子。1