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(4R,5S)-4-Methyl-5-phenyl-2-oxazolidinone_Molecular_structure_CAS_77943-39-6)
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(4R,5S)-4-Methyl-5-phenyl-2-oxazolidinone

Catalog No. 68700 Name Sigma Aldrich
CAS Number 77943-39-6 Website http://www.sigmaaldrich.com
M. F. C10H11NO2 Telephone 1-800-521-8956
M. W. 177.19984 Fax
Purity ≥99.0% (sum of enantiomers, GC) Email
Storage Chembase ID: 144802

SYNONYMS

Title
(4R,5S)-4-甲基-5-苯基-2-噁唑啉酮
IUPAC name
(4R,5S)-4-methyl-5-phenyl-1,3-oxazolidin-2-one
IUPAC Traditional name
(4R,5S)-4-methyl-5-phenyl-1,3-oxazolidin-2-one

DATABASE IDS

CAS Number 77943-39-6
PubChem SID 24885704
MDL Number MFCD00010845
Beilstein Number 1211705

PROPERTIES

Empirical Formula (Hill Notation) C10H11NO2
Grade purum
Purity ≥99.0% (sum of enantiomers, GC)
Melting Point 118-121 °C
Optical Rotation [α]20/D +160±3°, c = 1% in chloroform
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
German water hazard class 3

DETAILS

Description (English)
Other Notes
The 3-acyl derivatives are used in many enantioselective reactions: aldol, alkylation and acylation reactions1,2,3; the 3-acrylate derivatives in DA cycloadditions4
Description (简体中文)
Other Notes
该 3-酰基衍生物可用于很多对映选择性反应:羟醛反应、烷化反应以及酰化反应1,2,3;其 3-丙烯酸酯衍生物用于 DA 环加成反应4

REFERENCES