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α-Methylene-γ-butyrolactone_Molecular_structure_CAS_547-65-9)
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α-Methylene-γ-butyrolactone

Catalog No. 66735 Name Sigma Aldrich
CAS Number 547-65-9 Website http://www.sigmaaldrich.com
M. F. C5H6O2 Telephone 1-800-521-8956
M. W. 98.09994 Fax
Purity ≥97.0% (GC) Email
Storage Chembase ID: 150925

SYNONYMS

Title
α-亚甲基-γ-丁内酯
IUPAC name
3-methylideneoxolan-2-one
IUPAC Traditional name
tulipalin A
Synonyms
2-甲烯基丁内酯
3-Methylenedihydro-2(3H)-furanone
alpha-Methylene-gamma-butyrolactone
Tulipane

DATABASE IDS

CAS Number 547-65-9
Beilstein Number 107939
MDL Number MFCD00005407
PubChem SID 24884906

PROPERTIES

Contains ~1% 2,6-di-tert-butyl-4-methylphenol as stabilizer
Empirical Formula (Hill Notation) C5H6O2
Grade purum
Purity ≥97.0% (GC)
Boiling Point 86-88 °C/12 mmHg(lit.)
Density 1.119 g/mL at 25 °C(lit.)
Flash Point 37 °C
Flash Point 98.6 °F
Refractive Index n20/D 1.472(lit.)
Refractive Index n20/D 1.472
GHS Pictograms GHS02
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H226-H317
European Hazard Symbols Harmful Harmful (Xn)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P280
Risk Statements 10-42/43
Safety Statements 23-36/37-45
Storage Temperature 2-8°C
German water hazard class 3

DETAILS

Description (English)
Application
Very reactive Michael-acceptor; the α-methylene-γ-butyrolactone ring system exists in many natural products of biological interest
Description (简体中文)
Application
强反应性 Michael 受体;α-亚甲基-γ-丁内酯环系存在于许多具有生物学意义的天然产物中

REFERENCES