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Bromotrimethylsilane

Catalog No. 92337 Name Sigma Aldrich
CAS Number 2857-97-8 Website http://www.sigmaaldrich.com
M. F. C3H9BrSi Telephone 1-800-521-8956
M. W. 153.09306 Fax
Purity ≥97.0% (AT) Email
Storage Chembase ID: 78793

SYNONYMS

Title
溴三甲基硅烷
IUPAC name
bromotrimethylsilane
IUPAC Traditional name
bromotrimethylsilane
Synonyms
三甲基溴化硅
TMBS
Trimethylsilyl bromide
Trimethylbromosilane
三甲基溴硅烷

DATABASE IDS

CAS Number 2857-97-8
MDL Number MFCD00000048
EC Number 220-672-0
Beilstein Number 1731135

PROPERTIES

Purity ≥97.0% (AT)
Contains silver wool as stabilizer
Grade purum
Linear Formula (CH3)3SiBr
Boiling Point 79 °C(lit.)
Density 1.16 g/mL at 25 °C(lit.)
Flash Point 25 °C
Flash Point 77 °F
Refractive Index n20/D 1.424(lit.)
Refractive Index n20/D 1.424
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H226-H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 2920 8/PG 2
Risk Statements 10-14-34
Safety Statements 16-26-36/37/39-45
Storage Temperature 2-8°C
Supplemental Hazard Statements Reacts violently with water.
Hazard Class 8
UN Number 2920
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Other Notes
Powerful silylating agent 1,2; Cleavage of ethers 3; Smooth cleavage of phosphonic and phosphoric alkyl esters 4
Description (简体中文)
Other Notes
强效甲硅烷基化试剂1,2;用于醚的裂解3;以及膦酸和磷酸烷基酯的平稳裂解4

REFERENCES