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Tin(II) trifluoromethanesulfonate_Molecular_structure_CAS_62086-04-8)
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Tin(II) trifluoromethanesulfonate

Catalog No. 96565 Name Sigma Aldrich
CAS Number 62086-04-8 Website http://www.sigmaaldrich.com
M. F. C2F6O6S2Sn Telephone 1-800-521-8956
M. W. 416.8392192 Fax
Purity ≥97.0% (T) Email
Storage Chembase ID: 9816

SYNONYMS

Title
三氟甲烷磺酸锡
IUPAC name
λ2-tin(2+) ion ditrifluoromethanesulfonate
IUPAC Traditional name
λ2-tin(2+) ion ditriflate
Synonyms
三氟甲磺酸锡
Tin(II) triflate
Sn(OTf)2
Stannous trifluoromethanesulfonate
三氟甲烷磺酸锡(II)

DATABASE IDS

MDL Number MFCD00191251
PubChem SID 24890319
CAS Number 62086-04-8

PROPERTIES

Grade purum
Linear Formula (CF3SO3)2Sn
Purity ≥97.0% (T)
Melting Point ≥300 °C(lit.)
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 3261 8/PG 2
Risk Statements 34
Safety Statements 26-36/37/39-45
Hazard Class 8
UN Number 3261
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Application
Mild Lewis acid used for stereoselective aldol and Michael reactions; [2,3]-Wittig and Ireland-Claisen rearrangements; Horner-Wadsworth-Emmons reactions; asymmetric [3 + 2] cycloaddition; ring opening reactions; and Friedel-Crafts Reactions
Description (简体中文)
Application
Mild Lewis acid used for stereoselective aldol and Michael reactions; [2,3]-Wittig and Ireland-Claisen rearrangements; Horner-Wadsworth-Emmons reactions; asymmetric [3 + 2] cycloaddition; ring opening reactions; and Friedel-Crafts Reactions

REFERENCES