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(S)-(+)-Acetyl-cyclopentadienyl-iron carbonyl triphenylphosphine complex_Molecular_structure_CAS_36548-60-4)
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(S)-(+)-Acetyl-cyclopentadienyl-iron carbonyl triphenylphosphine complex

Catalog No. 01037 Name Sigma Aldrich
CAS Number 36548-60-4 Website http://www.sigmaaldrich.com
M. F. C26H23FeO2P Telephone 1-800-521-8956
M. W. 454.278381 Fax
Purity ≥97.0% (sum of enantiomers, HPLC) Email
Storage Chembase ID: 158140

SYNONYMS

Title
(S)-(+)-乙酰-环戊二烯基铁复杂羰三苯基膦
IUPAC name
acetylironylium; cyclopenta-2,4-dien-1-ide; methanidylidyneoxidanium; triphenylphosphane
IUPAC Traditional name
acetylironylium; carbon monoxide; cyclopentadienide; triphenylphosphine
Synonyms
‘Iron acetyl chiral’
(S)-(+)-Cyclopentadienyl iron acetyl carbonyl triphenylphosphine complex
“手性乙酰基铁"

DATABASE IDS

MDL Number MFCD00148973
PubChem SID 24845129
CAS Number 36548-60-4

PROPERTIES

Empirical Formula (Hill Notation) C26H23FeO2P
Grade purum
Purity ≥97.0% (sum of enantiomers, HPLC)
Melting Point 151-156 °C
Optical Rotation [α]20/D +175±10°, c = 0.04% in benzene
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Storage Temperature 2-8°C
German water hazard class 3

DETAILS

Description (English)
Other Notes
Chiral organometallic auxiliary for several C-C bond forming reactions
Description (简体中文)
Other Notes
手性有机金属助剂,用于各种 C-C 成键反应

REFERENCES