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Trifluoroacetic anhydride_Molecular_structure_CAS_407-25-0)
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Trifluoroacetic anhydride

Catalog No. 91720 Name Sigma Aldrich
CAS Number 407-25-0 Website http://www.sigmaaldrich.com
M. F. C4F6O3 Telephone 1-800-521-8956
M. W. 210.0314192 Fax
Purity ≥99.0% (GC) Email
Storage Chembase ID: 99501

SYNONYMS

Title
三氟乙酸酐
IUPAC name
trifluoroacetyl 2,2,2-trifluoroacetate
IUPAC Traditional name
trifluoroacetic anhydride
Synonyms
TFAA

DATABASE IDS

Beilstein Number 746197
CAS Number 407-25-0
MDL Number MFCD00000416
EC Number 206-982-9

PROPERTIES

Grade purum
Linear Formula (CF3CO)2O
Purity ≥99.0% (GC)
Boiling Point 39.5-40 °C(lit.)
Density 1.511 g/mL at 20 °C(lit.)
Melting Point -65 °C(lit.)
Refractive Index n20/D 1.3(lit.)
Vapor Pressure 6.28 psi ( 20 °C)
GHS Pictograms GHS05
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H314-H332-H412
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US)
GHS Precautionary statements P273-P280-P305 + P351 + P338-P310
RID/ADR UN 3265 8/PG 1
Risk Statements 14-20-35-52/53
RTECS AJ9800000
Safety Statements 26-36/37/39-43-45-61
Storage Temperature 2-8°C
Supplemental Hazard Statements Reacts violently with water.
Hazard Class 8
UN Number 3265
Packing Group 1
German water hazard class 2

DETAILS

Description (English)
Other Notes
Powerful activator in the DMSO oxidation of alcohols to carbonyl compounds1,2
Description (简体中文)
Other Notes
在 DMSO 中将醇氧化成羰基化合物的强效活化剂1,2

REFERENCES